ArticleAngewandte Chemie (International ed. in English)2026
In Situ Converted High-Loading Membranes With Molecularly Dispersed Porous Organic Cages for Superior CO
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Porous organic cages (POCs) based mixed-matrix membranes with characteristics of molecular-size pores and operation efficiency are promising for gas separation; however, the imbalance between high loading and molecular dispersion impedes the further development of POCs in the field of membrane gas separation. Herein, we propose an in situ cage conversion strategy to construct solid-solution membranes: RCC3, a highly soluble yet nonporous cage, is first synthesized via the reduction reaction, followed by its homogeneous dispersion in PIM-1 to form a uniform membrane. Paraformaldehyde, involved in situ nucleophilic addition, converts nonporous RCC3 to rigid porous FT-RCC3 directly in the membrane. FT-RCC3 membrane exhibits permanent porosity and molecularly dispersed cages with the highest loading (26.6 wt%) achieved ever for POC-based membranes. Permeation measurements of CO
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