ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Lewis-Acid Engineering with Neodymium Promoters as Synergistic Nd-Ni Dual Sites for Enhanced Urea Oxidation.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The sluggish kinetics of the urea oxidation reaction (UOR) are strongly associated with the high energy barriers required for the C-N cleavage and N-N coupling steps. While nickel-based catalysts are promising, their performance is limited by high operational potentials and structural instability. This work introduces neodymium (Nd) as a Lewis acid site promoter into a nickel-based framework to create Nd-Ni oxide catalysts. The strong Lewis acidity of Nd centers enhances urea adsorption and facilitates C-N cleavage and N-N coupling, while the significant electronegativity difference between Nd and Ni induces electronic redistribution for optimizing intermediate adsorption for UOR. As a result, the optimal catalyst demonstrates superior UOR performance, in which a low potential of 1.347 V is required to achieve 10 mA cm
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