Evidence map›Paper›PMID 42163593›Full record

ArticleAdvanced materials (Deerfield Beach, Fla.)2026

High-Efficiency Organic Solar Cells Enabled by Siloxane-Functionalized Pyrazine Terpolymers: Synergizing Performance, Morphology Control, and Non-Halogenated Solvent Processability.

Wenwen Hou, Jingnan Wu, Bo Cheng, Chenyu Han, Fengbo Sun, Yumiao Huo, Hao Wang, Jun Sun, Lixuan Kan, Leandro Rezende Franco and 6 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

16 authors.

Wenwen HouNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.
Jingnan WuDepartment of Chemistry and Chemical Engineering, Chalmers University of Technology, Göteborg, Sweden.ORCID https://orcid.org/0000-0002-9868-3721
Bo ChengNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.
Chenyu HanNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.
Fengbo SunNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.
Yumiao HuoNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.
Hao WangNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.
Jun SunNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.
Lixuan KanSchool of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Center of Hydrogen Science, Center of Physical Science, Shanghai Jiao Tong University, Shanghai, China.
Leandro Rezende FrancoDepartment of Chemistry and Chemical Engineering, Chalmers University of Technology, Göteborg, Sweden.
Xinxin XiaNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.
Feng LiuSchool of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Center of Hydrogen Science, Center of Physical Science, Shanghai Jiao Tong University, Shanghai, China.
Ergang WangDepartment of Chemistry and Chemical Engineering, Chalmers University of Technology, Göteborg, Sweden.
Xia GuoNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.
Yongfang LiSuzhou Key Laboratory of Novel Semiconductor-Optoelectronics Materials and Devices, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, China.
Maojie ZhangNational Engineering Research Center for Colloidal Materials, Key Laboratory of Special Functional Aggregated Materials (Shandong University), Ministry of Education, School of Chemistry & Chemical Engineering, Shandong University, Jinan, Shandong, China.ORCID https://orcid.org/0000-0002-6102-5856

Funding

Shandong Provincial Natural Science Foundation ZR2022JQ09Taishan Scholar Program at Shandong Province tsqn202306061
6 · The paper itself

Abstract

Balancing high performance, morphological controllability, and compatibility with non-halogenated solvent processing remains a critical bottleneck for scalable and sustainable organic solar cells (OSCs). Herein, we address this challenge via rational terpolymer design: integrating a siloxane-functionalized electron-deficient pyrazine unit (DTCPz-SiO) into the benchmark D18 backbone, with the optimized terpolymer DN1 containing 5 mol% DTCPz-SiO. DTCPz-SiO imparts two key synergies: (i) enhanced conformational rigidity and intramolecular noncovalent interactions (N···S, N···H), which improve backbone planarity, strengthen π-π stacking, and accelerate crystallization; (ii) synergistic regulation of donor-acceptor miscibility and compatibility with non-halogenated solvents. These effects collectively enable a well-optimized bulk-heterojunction morphology with enhanced molecular ordering and charge dynamics. Consequently, DN1-based binary devices deliver a significantly improved power conversion efficiency (PCE) of 20.1% compared to 18.7% for the parent polymer, together with a broadened processing window. Notably, high efficiencies of ∼19.5% are retained under common non-halogenated processing conditions. Furthermore, DN1-based ternary OSCs enhance PCE to outstanding values of 20.9% and 20.0% under chlorinated and non-halogenated processing conditions, respectively, among the highest efficiencies reported for single-junction OSCs. Overall, this work establishes siloxane-functionalized terpolymers as an effective molecular design strategy for regulating multi-scale morphology and processing tolerance, providing new insights for the development of scalable OSC systems.

Indexed as

morphological controlnon‐halogenated solvent processingorganic solar cellsrandom terpolymerization

Identifiers

PMID42163593
PMCPMC13288202

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.