ArticleAdvanced materials (Deerfield Beach, Fla.)2026
A Restacking Inhibited Carbonization Pathway for Graphitization-Prone Precursors Toward Long-Life Sodium-Ion Batteries.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Theory-guided design of hard carbon anode from graphitization-prone precursors remains challenging because oxidation and carbonization routes lack mechanisms to selectively disrupt ordered π-π stacking while preserving structural integrity during carbonation for performance. We propose an intrinsic heteroatom-assisted site-preferential oxidation mechanism that enables framework disruption and kinetically inhibits restacking during carbonization of petroleum asphaltenes rich in heteroatoms. Electronic inhomogeneity of nitric acid makes its acid-derived radicals preferentially anchor on heteroatom-modified sites, inducing steric hindrance and oxidation-guided pore evolution that yields turbostratic hard carbon with expanded interlayer spacing and closed pores. Operando characterization and density functional theory (DFT) calculations identified this heteroatom-mediated localized reactivity as the origin of suppressed graphitization and enhanced sodium-storage kinetics. The resulting material delivers a high initial Coulombic efficiency (ICE) of 89.7% and a reversible capacity of 404.1 mAh g
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