ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Artificial Crystalline-Amorphous Architecture Enables Continuous Ion Transport in Poly(Vinylidene Fluoride)-Based Solid-State Electrolytes.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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12 authors.
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Abstract
Solid-state polymer electrolytes (SPEs) hold promises for next-generation batteries but are hindered by low ionic conductivities. This issue stems from crystalline regions that block long-range ion transport in amorphous phases, while fully amorphous polymers are mechanically unstable. Here we design an "artificial crystalline-amorphous" architecture that converts the isolated amorphous conduction zones into continuous, long-range pathways. This is achieved by infiltrating a fully amorphous poly (vinylidene fluoride‑co‑chlorotrifluoroethylene) (PVT) into an oriented electrospun fibrous framework of polar semi‑crystalline PVT. The framework serves as an "artificial crystalline phase," offering robust mechanical support and facilitating lithium‑salt dissociation. Simultaneously, the amorphous phase utilizes this microscale network to enable long-range ion conduction. The resulting SPEs exhibit an extremely high ionic conductivity of 1.23 mS cm
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