ArticleChemical science2026
Dynamic pendulum strategy enables both anti-quenching and fast spin flipping for efficient blue multiple-resonance thermally activated delayed fluorescence emitters.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Multiple-resonance thermally activated delayed fluorescence (MR-TADF) emitters have attracted considerable interest due to their superiority in high-resolution organic light-emitting diodes (OLEDs), but suffer from severe aggregation-caused quenching and slow reverse intersystem crossing. Herein, a dynamic pendulum strategy is proposed, in which electron donors are tethered to the classic boron-nitrogen MR core (BCzBN) by employing an oxygen atom as a flexible anchoring point. Benefitting from the distinctive oxygen linkage and dynamic swinging behavior, the resultant MR-TADF emitters can access multiple isomeric conformations, thereby simultaneously achieving blue-shifted emission, preserved narrow full width at half maximum, enhanced quenching resistance, and faster spin flipping compared with BCzBN. As a consequence, the corresponding OLEDs achieve bright blue narrowband electroluminescence in an extremely wide doping window of 1-30 wt%, revealing a record-high external quantum efficiency of 30.4% even at 20 wt%. The results clearly highlight the great potential of the dynamic pendulum strategy for efficient blue MR-TADF emitters.
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