Evidence map›Paper›PMID 42157888›Full record

ArticleChemical science2026

Dynamic pendulum strategy enables both anti-quenching and fast spin flipping for efficient blue multiple-resonance thermally activated delayed fluorescence emitters.

Xiangqin Gan, Bitian Chen, Jia-Qi Li, Han Si, Ning Sun, Guoyun Meng, Xian-Kai Chen, Liming Ding, Zheng-Hong Lu, Junqiao Ding

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Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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4 · The record

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5 · Who and what money

Authors and funding

10 authors.

Xiangqin GanKey Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, National Center for International Joint Research of Photoelectronic Energy Materials and Application Kunming 650091 P. R. China dingjunqiao@ynu.edu.cn mengguoyun@ynu.edu.cn sihan94720@outlook.com.
Bitian ChenKey Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, National Center for International Joint Research of Photoelectronic Energy Materials and Application Kunming 650091 P. R. China dingjunqiao@ynu.edu.cn mengguoyun@ynu.edu.cn sihan94720@outlook.com.
Jia-Qi LiInstitute of Functional Nano and Soft Materials (FUNSOM), Soochow University Suzhou Jiangsu 215123 P. R. China xkchen@suda.edu.cn.
Han SiKey Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, National Center for International Joint Research of Photoelectronic Energy Materials and Application Kunming 650091 P. R. China dingjunqiao@ynu.edu.cn mengguoyun@ynu.edu.cn sihan94720@outlook.com.
Ning SunSchool of Physics and Astronomy, Yunnan University Kunming 650091 P. R. China.
Guoyun MengKey Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, National Center for International Joint Research of Photoelectronic Energy Materials and Application Kunming 650091 P. R. China dingjunqiao@ynu.edu.cn mengguoyun@ynu.edu.cn sihan94720@outlook.com.
Xian-Kai ChenInstitute of Functional Nano and Soft Materials (FUNSOM), Soochow University Suzhou Jiangsu 215123 P. R. China xkchen@suda.edu.cn.
Liming DingSchool of Chemical Engineering and Light Industry, Guangdong University of Technology Guangzhou 510006 P. R. China.ORCID https://orcid.org/0000-0001-6437-9150
Zheng-Hong LuSchool of Physics and Astronomy, Yunnan University Kunming 650091 P. R. China.ORCID https://orcid.org/0000-0003-2050-0822
Junqiao DingKey Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, National Center for International Joint Research of Photoelectronic Energy Materials and Application Kunming 650091 P. R. China dingjunqiao@ynu.edu.cn mengguoyun@ynu.edu.cn sihan94720@outlook.com.ORCID https://orcid.org/0000-0001-7719-6599

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Multiple-resonance thermally activated delayed fluorescence (MR-TADF) emitters have attracted considerable interest due to their superiority in high-resolution organic light-emitting diodes (OLEDs), but suffer from severe aggregation-caused quenching and slow reverse intersystem crossing. Herein, a dynamic pendulum strategy is proposed, in which electron donors are tethered to the classic boron-nitrogen MR core (BCzBN) by employing an oxygen atom as a flexible anchoring point. Benefitting from the distinctive oxygen linkage and dynamic swinging behavior, the resultant MR-TADF emitters can access multiple isomeric conformations, thereby simultaneously achieving blue-shifted emission, preserved narrow full width at half maximum, enhanced quenching resistance, and faster spin flipping compared with BCzBN. As a consequence, the corresponding OLEDs achieve bright blue narrowband electroluminescence in an extremely wide doping window of 1-30 wt%, revealing a record-high external quantum efficiency of 30.4% even at 20 wt%. The results clearly highlight the great potential of the dynamic pendulum strategy for efficient blue MR-TADF emitters.

Identifiers

PMID42157888
PMCPMC13182275

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.