ArticleJournal of the American Chemical Society2026
Torsional Ordering as a Prerequisite for Zeolite Crystallization Revealed by X-ray Emission Spectroscopy.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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11 authors.
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Abstract
Understanding how ordered crystals emerge from disordered precursors is a grand challenge in materials science. Resolving this question is critical for tailoring the properties of network materials, particularly zeolitic silicates, which are indispensable in energy and environmental catalysis. This challenge has been particularly acute as the key three-dimensional (3D) ordering of the silicate network has remained experimentally inaccessible. However, detailed knowledge of crystallization would enable tailoring of key properties for improved applications. Here, we provide direct observation of this process using O 1s X-ray emission spectroscopy (XES) as a spectroscopic ruler for the 3D network geometry. Supported by
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