Evidence map›Paper›PMID 42154669›Full record

ArticleJournal of the American Chemical Society2026

Transient Triamidoamine Neptunium(V)-Mono(Imido) Complexes: C-H Activations and Hydrogen Atom Transfer Driven by Effective Nuclear Charge.

Michał S Dutkiewicz, Iskander Douair, Jingzhen Du, Conrad A P Goodwin, Leonardo Tacconi, Mauro Perfetti, Andrew J Gaunt, Samuel M Greer, Benjamin W Stein, Roberto Caciuffo and 9 more

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

19 authors.

Michał S DutkiewiczDepartment of Chemistry and Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Iskander DouairLPCNO, CNRS and INSA, Université Paul Sabatier, 135 Avenue de Rangueil, Toulouse 31077, France.ORCID 0000-0002-7482-5510
Jingzhen DuDepartment of Chemistry and Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.ORCID 0000-0003-4037-9281
Conrad A P GoodwinDepartment of Chemistry and Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.ORCID 0000-0002-4320-2548
Leonardo TacconiDepartment of Chemistry Ugo Schiff, University of Florence, Via della Lastruccia 3, 50019 Sesto Fiorentino, Italy.ORCID 0009-0003-5145-1047
Mauro PerfettiDepartment of Chemistry Ugo Schiff, University of Florence, Via della Lastruccia 3, 50019 Sesto Fiorentino, Italy.ORCID 0000-0001-5649-0449
Andrew J GauntChemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States.ORCID 0000-0001-9679-6020
Samuel M GreerChemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States.ORCID 0000-0001-8225-3252
Benjamin W SteinChemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States.ORCID 0000-0002-0366-5476
Roberto CaciuffoEuropean Commission, Joint Research Centre, Postfach 2340, 76125 Karlsruhe, Germany.
Eric ColineauEuropean Commission, Joint Research Centre, Postfach 2340, 76125 Karlsruhe, Germany.
Jean-Christophe GriveauEuropean Commission, Joint Research Centre, Postfach 2340, 76125 Karlsruhe, Germany.
John A SeedDepartment of Chemistry and Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.ORCID 0000-0002-3751-0325
Attila KovácsEuropean Commission, Joint Research Centre, Postfach 2340, 76125 Karlsruhe, Germany.ORCID 0000-0001-8169-3547
Brian L ScottMaterials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States.
Ashley J WoolesDepartment of Chemistry and Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.ORCID 0000-0001-7411-9627
Laurent MaronLPCNO, CNRS and INSA, Université Paul Sabatier, 135 Avenue de Rangueil, Toulouse 31077, France.ORCID 0000-0003-2653-8557
Olaf WalterEuropean Commission, Joint Research Centre, Postfach 2340, 76125 Karlsruhe, Germany.ORCID 0000-0002-2679-1715
Stephen T LiddleDepartment of Chemistry and Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.ORCID 0000-0001-9911-8778

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metal-mono(imido) linkages have been known for seven decades, and they are found in transition metal, main group, lanthanide, thorium, and uranium complexes. However, transuranium-mono(imido) complexes remain unknown in any scenario. Here, we present evidence for transient neptunium(V)-mono(imido) complexes. Treatment of [Np

Identifiers

PMID42154669
PMCPMC13244476

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.