Record-Breaking Asymmetric Hysteresis Width Greater Than 100 K Spanning Room Temperature in Mn(III)-Based Spin-Crossover Materials Enabled by 2D Hydrogen-Bonding Cooperativity.

Anangamohan Panja, Zvonko Jagličić, Paula Brandão, Narayan Ch Jana

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

4 authors.

Anangamohan PanjaDepartment of Chemistry, Gokhale Memorial Girls' College, Kolkata, India.ORCID https://orcid.org/0000-0002-6864-0501

Zvonko JagličićInstitute of Mathematics, Physics and Mechanics & Faculty of Civil and Geodetic Engineering, University of Ljubljana, Ljubljana, Slovenia.

Paula BrandãoDepartment of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, Aveiro, Portugal.ORCID https://orcid.org/0000-0002-4746-6073

Narayan Ch JanaDepartment of Chemistry, Panskura Banamali College, Panskura RS, India.ORCID https://orcid.org/0000-0002-2849-5784

Funding

CICECO-Aveiro Institute of Materials LA/P/0006/2020CICECO-Aveiro Institute of Materials UID/50011/2025CSIR, New Delhi 01/3118/23/EMR-IISlovenian Research Agency P2-0348

6 · The paper itself

Abstract

Spin crossover (SCO) materials capable of exhibiting wide thermal hysteresis loops near room temperature are highly desirable for molecular switches, memory devices, and sensors. While such behavior has been extensively studied in Fe(II), Fe(III), and Co(II) complexes, examples in Mn(III)-based systems remain limited due to the typically favored high-spin state and subtle structural changes accompanying spin-state switching. Herein, we report a Mn(III)-based spin-crossover complex [Mn(3-MeO-5-Me-sal

Indexed as

2D hydrogen bonding networkMn(III) complexesspin crossoversupramolecular cooperativitythermal hysteresis

Identifiers

PMID42154578

DOI10.1002/anie.8070182

PMCPMC13427106

What OpenQuestion holds

Textmetadata

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.