A New Metal-Ester Bonding Motif for the Synthesis of Hybrid Molecular Catalysts on Metal Oxide Supports Leads to Tunable Reactivity.

Joseph J Kuchta, Sarah M Moody, Alexia M Bradbury, D M S C Dissanayake, Laura C Maybach, Santosh K Balijepalli, John R Regalbuto, Aaron K Vannucci

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Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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8 authors.

Joseph J KuchtaDepartment of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, USA.ORCID https://orcid.org/0009-0004-7834-7220

Sarah M MoodyDepartment of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, USA.

Alexia M BradburyDepartment of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, USA.

D M S C DissanayakeDepartment of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, USA.

Laura C MaybachDepartment of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, USA.ORCID https://orcid.org/0009-0009-3724-3851

Santosh K BalijepalliOffice of Vice President For Research, University of South Carolina, Columbia, South Carolina, USA.ORCID https://orcid.org/0000-0003-1188-6831

John R RegalbutoDepartment of Chemical Engineering, University of South Carolina, Columbia, South Carolina, USA.ORCID https://orcid.org/0000-0002-5785-0749

Aaron K VannucciDepartment of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, USA.ORCID https://orcid.org/0000-0003-0401-7208

Funding

National Science Foundation 1954850

6 · The paper itself

Abstract

The synthesis, characterization, and structure-function properties for a new class of hybrid catalysts comprised of molecular catalysts with ligands covalently bound to metal oxide (MOx) supports via metal-ester bonds is reported. Anchoring molecular catalysts to metal-oxides through the ligand structure is an important motif for dye-sensitized solar cells, electrocatalysis, and thermally driven catalysis. This new motif is amenable to a wide variety of metal oxide supports. Data show this new surface binding motif is able to achieve catalyst surface loadings of up to two molecules per nm

Identifiers

PMID42154576

DOI10.1002/anie.1483240

PMCPMC13360733

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