ArticleNature communications2026
Oxidative stability as a guiding principle for durable ionomer cations in pure-water electrolysis.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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11 authors.
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Abstract
Cation degradation in ionomers critically limits the durability of pure-water-fed anion exchange membrane water electrolysis, particularly at the anode where high overpotentials and near-neutral pH induce harsh oxidative stress. However, prevailing cation design remains rooted in alkali-stability frameworks, which fall short under these oxidative conditions. Here, a multiscale approach combining molecular degradation and operando diagnostics identifies electrochemical oxidation as the dominant anodic cation degradation pathway in anion exchange membrane water electrolysis, prompting a shift toward oxidation-resistant cation design. Electrolyzers incorporating oxidation-tolerant trimethylammonium-functionalized ionomers achieve 360-hour stability at 1 A cm⁻
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