ArticleSmall science2026
Quantifying and Leveraging Interfacial Amine Reactivity in Block Copolymer Nanoparticles for Advanced Material Design.
Article in Small science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
7 authors.
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Abstract
The rational design of functional nanomaterials requires precise control over molecular architecture and interfacial reactivity. Here, we report the synthesis of amine-functionalized block copolymer nanoparticles via aqueous polymerization-induced self-assembly, combining synthetic efficiency with rigorous characterization to bridge molecular design and macroscopic functionality. The incorporation of 2-aminoethyl methacrylate into a macrochain transfer agent enabled the formation of stable, monodisperse nanoparticles while providing quantifiable interfacial amines for postassembly modification. Near-quantitative conjugation with fluorescein isothiocyanate (86% yield) or thermoresponsive poly(
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