Evidence map›Paper›PMID 42146759›Full record

ArticleChem catalysis2025

Photocatalysis as a mechanistic probe for the Staudinger β-lactam synthesis.

Mihai V Popescu, Nicholas A Parker, Zhuqing Jia, Pearse Solon, Callan J Maloney, Juan V Alegre-Requena, Robert S Paton, Martin D Smith

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chem catalysis, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Mihai V PopescuChemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK.
Nicholas A ParkerChemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK.
Zhuqing JiaChemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK.
Pearse SolonChemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK.
Callan J MaloneyChemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK.
Juan V Alegre-RequenaDepartamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC-Universidad de Zaragoza, Calle Pedro Cerbuna 12, Zaragoza 50009, Spain.
Robert S PatonDepartment of Chemistry, Colorado State University, 1301 Centre Avenue, Fort Collins, CO 80523-1872, USA.
Martin D SmithChemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK.

Funding

Computational Models for New Developments in Radical ChemistryR01GM151533 · NIGMS · COLORADO STATE UNIVERSITY · PI Robert Scott Paton · 2023 to 2026
$1.2M
NIGMS NIH HHS R01 GM151533
6 · The paper itself

Abstract

In this study, we demonstrate that a visible-light-mediated energy transfer process can serve as a mechanistic probe in the Staudinger cyclization. Ikeda demonstrated that N-acyl enaminone substrates undergo diastereoselective cyclization to form

Identifiers

PMID42146759
PMCPMC13175146

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.