ArticleACS omega2026
Thermophysical Properties and Molecular Dynamics Insights into Glycolic Acid-Sorbitol NaDES-Water Mixtures.
Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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7 authors.
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Abstract
Natural deep eutectic solvents (NaDES) have emerged as a sustainable alternative to traditional organic solvents due to their easy preparation, biodegradability, low toxicity, and high chemical stability. NaDESs are formed and their physicochemical properties can be tailored by solvent addition and water content. In this study, density, viscosity, and electrical conductivity of binary mixtures composed of glycolic acid and sorbitol (3:1) NaDES and water were investigated. The results show a reduction in density and viscosity with increasing temperature and water mole fraction, while conductivity increases up to a maximum near a water mole fraction of 0.9 and decreases in the water-rich region. Excess molar volumes and viscosity deviations were calculated and correlated using the Redlich-Kister equation. FTIR spectroscopy and molecular dynamics simulations revealed that hydrogen-bond interactions between NaDES components and water are progressively weakened with increasing water content, explaining the observed changes in transport properties.
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