ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Mechanistic Insights Into the Transition-Metal-Catalyzed Dual Reactivity Mode of Vinyl Ethylene Carbonates With Anilines.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- Mechanistic Insights Into the Transition-Metal-Catalyzed Dual Reactivity Mode of Vinyl Ethylene Carbonates With Anilines.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
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3 authors.
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Abstract
A study into a catalyst-controlled chemodivergent strategy to access 2-vinyl indolines and indole-2-acetates is presented herein. This strategy overcomes the usual allylic reactivity of vinyl ethylene carbonates (VECs) via a tandem C─H/C─O bond activation sequence. The methodology provides useful molecular scaffolds by following two distinct pathways in a highly step- and atom-economical manner and features a challenging β-hydroxide elimination. In the Rh-catalyzed transformation, unusual competing pathways were observed, such as a regioselective insertion of a Rh-OMe species into the "C═C" bond of the vinyl segment, a regioselective C─H activation of the vinyl indoline, and an interesting oxidative addition of MeOH into Rh(I). Detailed mechanistic insights through a combination of experimental and computational studies unveil a unique reactivity mode of VECs, thereby opening up a new avenue for transition metal catalysis. Synthetic utility of the annulated products demonstrates an additional advantage of the methodology.
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