ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Structural Origin of Crystallographic Face-Dependent Elastoplastic and Plastic Bending in an Organic Molecular Crystal.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Crystalline materials that exhibit attractive mechanical responses under external stresses have attracted considerable interest due to their potential applications across multiple fields. Here, we present a crystalline form of 9-fluorenone hydrazone (9-FH) that exhibits dual mechanical stress response, that is, plasticity and elastoplastic behavior, on different crystallographic faces. This dual mechanical response arises from specific molecular packing features, wherein intermolecular interactions play a key role in modulating the crystal's mechanical properties from the different faces. Here, large 9-FH single crystals demonstrate excellent plastic behavior under applied forces, attributed to the reorganization of weak interactions across the slip planes. Moreover, this comprehensive analysis offers detailed insights into the distinct mechanical responses of 9-FH and the underlying mechanism.
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