ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Cyclen Tetra-Amide Ligands as a Privileged Class of Ligands for Studying Second-Sphere Coordination Environments.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
We propose that derivatives of cyclen tetra-amides are a privileged class of ligands for large ions such as lanthanides that enable control over the second-coordination sphere environment of discrete complexes. We demonstrate this concept first through highlighting examples of lanthanide cyclen tetra-amide derivatives that provide control over three different second-sphere environments. Control over the second-coordination sphere is then leveraged to enable the first mechanistic and kinetic oxidation studies of a Eu
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