ArticleJournal of the American Chemical Society2026
Through-Space Stabilization of Carbon-Centered Aryl Dicyanomethyl Radicals.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
5 authors.
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Abstract
Stable organic radicals have diverse applications in medicine, biology, materials, and quantum sciences. Understanding the factors that affect radical stability is essential for exploiting radicals for such applications. Aryl dicyanomethyl radicals are an intriguing class of carbon-centered radicals due to their notable air and thermal stabilities, but these species are known to dimerize to form sigma or pi dimers at low temperatures. However, whether such carbon-centered radicals could potentially be stabilized by exploiting through-space interactions remains unknown. To evaluate whether through-space stabilization is possible, aryl dicyanomethyl radicals with nitro groups in the
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