Dynamic Anion Space Gradient Distribution Drives Wide-Temperature-Range All-Solid-State Lithium-Ion Batteries.

Chao Li, Wenshuo Zhang, Zhenkun He, Zhen Yan, Zhichao Zeng, Xiaomeng Shi, Bin Kang, Yaping Du

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

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4 · The record

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5 · Who and what money

Authors and funding

8 authors.

Chao LiTianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, Frontier Science Center for New Organic Matter, Haihe Laboratory of Sustainable Chemical Transformations, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, People's Republic of China.

Wenshuo ZhangTianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, Frontier Science Center for New Organic Matter, Haihe Laboratory of Sustainable Chemical Transformations, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, People's Republic of China.

Zhenkun HeTianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, Frontier Science Center for New Organic Matter, Haihe Laboratory of Sustainable Chemical Transformations, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, People's Republic of China.

Zhen YanRare Earth Advanced Materials Technology Innovation Center, Inner Mongolia Northern Rare Earth Advanced Materials Technology Innovation Co., Ltd, Baotou, People's Republic of China.

Zhichao ZengTianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, Frontier Science Center for New Organic Matter, Haihe Laboratory of Sustainable Chemical Transformations, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, People's Republic of China.

Xiaomeng ShiTianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, Frontier Science Center for New Organic Matter, Haihe Laboratory of Sustainable Chemical Transformations, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, People's Republic of China.

Bin KangRare Earth Advanced Materials Technology Innovation Center, Inner Mongolia Northern Rare Earth Advanced Materials Technology Innovation Co., Ltd, Baotou, People's Republic of China.

Yaping DuTianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, Frontier Science Center for New Organic Matter, Haihe Laboratory of Sustainable Chemical Transformations, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, People's Republic of China.ORCID https://orcid.org/0000-0002-9937-2087

Funding

National Natural Science Foundation of China 22305129National Natural Science Foundation of China 22371131National Science Foundation for Distinguished Young Scholars of China 22425503the 111 Project B18030the China Postdoctoral Science Foundation 2023M741812the Key Project of the Tianjin Natural Science Foundation 25JCZDJC01120the Project of the Department of Science and Technology of Inner Mongolia Autonomous Region XM2024XTGXQ13

6 · The paper itself

Abstract

To address the critical challenges of poor ionic conductivity, insufficient interfacial stability, and narrow operating temperature range in all-solid-state lithium batteries (ASSLBs), this work develops a dynamic anion functionalization strategy to design and synthesize a new class of yttrium-based rare-earth halide solid-state electrolytes (SSEs). It is found that the dynamic anions can not only statically modify the lattice but also undergo reversible dynamic migration during cycling, thereby transforming the traditional single-cation conductor into a cation-anion synergistic conductor, which significantly enhances the overall ionic conductivity. Furthermore, the dynamic anions facilitate a gradient LiF protection layer on the cathode side to improve high-voltage compatibility and form a dense Li

Indexed as

adaptive interface layercation‐anion synergistic conductordynamic anionionic conductivityrare‐earth

Identifiers

PMID42139106

DOI10.1002/anie.4333062

PMCPMC13382923

What OpenQuestion holds

Textmetadata

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.