ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Cellulose Nanocrystal/Zn-MOF Nanocarriers for Enhanced Foliar Adhesion, pH-Responsive Release, and Efficient Pesticide Delivery.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Stimuli-responsive nanopesticide delivery systems have attracted increasing attention due to their potential for controlled release and targeted application. However, their practical use in agriculture is often hindered by poor foliar retention, limited UV stability, and uncontrolled release behaviour. In this study, a grape-pedicel-like nanocarrier was constructed via in situ integration of cellulose nanocrystals (CNCs) with zeolitic imidazolate frameworks (ZnMOFs), which effectively encapsulated acetamiprid (Ace) and exhibited enhanced leaf adhesion and sustained-release performance. The release of ACE was triggered by naturally occurring organic acids (e.g., oxalic acid) generated during plant metabolism, enabling a pH-responsive behaviour under mildly acidic conditions (pH = 5). The cumulative release reached 85.9%, and the release kinetics followed the Ritger-Peppas model. Compared with commercial formulations, Ace@CNC/ZnMOFs showed superior dispersibility and significantly improved foliar adhesion (28.9 mg cm
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