ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Synchronizing Tunable Luminescence and Shape Morphing in a Metal Nanocluster-Enabled Hydrogel Platform.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Soft hydrogels capable of simultaneous shape morphing and optical modulation under a single stimulus hold promise for next-generation intelligent materials. However, most systems rely on complex architectures or multi-component triggers, limiting integration and responsiveness. Here, we develop a structurally homogeneous nanocluster-gel platform by embedding water-soluble gold nanoclusters (AuNCs) into a polyacrylamide matrix, enabling synchronized mechanical deformation and tunable luminescence in response to solvent polarity. Upon exposure to organic solvents, the gel rapidly contracts (<5 s), while spatial confinement of AuNCs within the polymer boosts quantum yield from 6.05% to 22.83%. The emission profile is programmable by varying cluster size, highlighting AuNCs as structurally tunable emission modulators. Kinetic analysis reveals non-Fickian swelling/deswelling-governed by solvent diffusion and polymer relaxation-that synergistically modulates emission. This enables real-time, quantitative optical detection of solvent gradients (R
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