ArticleOrganic letters2026
Sulfinylnitrenes via Chemoselective S-N Bond Cleavage: Design, Synthesis, and Applications.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
4 authors.
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Abstract
Herein, we report the development of bench-stable, scalable sulfinylnitrene precursors that enable the generation of reactive sulfinylnitrene intermediates via chemoselective S-N bond cleavage under thermal or photolytic conditions, without additives or pyrophoric reagents. These intermediates react with nucleophiles (N or O) to afford sulfonimidamides, a privileged pharmacophore, or sulfonimidates, a versatile intermediate in deoxygenating reactions. This operationally simple transformation provides a general strategy for S-N bond formation and enables late-stage functionalization of amines.
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Registered trials
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