ArticleChemical science2026
Chalcogen bonding-directed photoresponsive helix from azo-fused H-bonded arylamide foldamers.
Chuan-Zhi Liu, Chi Zhang, Hua-Shuo Zheng, Liu-Xin Luo, Shuang-Shuang Hou, Song-Hao Guo, Meng-Ge Zhang, Xin-Yao Peng, Liang Xu, Bin Zhai
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Chuan-Zhi LiuEngineering Research Centre for Optoelectronic Functional Materials of Henan Province, College of Chemistry and Chemical Engineering, Shangqiu Normal University Shangqiu Henan 476000 China liuchuanzhiuniv@163.com liuchuanzhi@sqnu.edu.cn zhaibin_1978@163.com.ORCID https://orcid.org/0000-0001-8539-339X Chi ZhangEngineering Research Centre for Optoelectronic Functional Materials of Henan Province, College of Chemistry and Chemical Engineering, Shangqiu Normal University Shangqiu Henan 476000 China liuchuanzhiuniv@163.com liuchuanzhi@sqnu.edu.cn zhaibin_1978@163.com.
Hua-Shuo ZhengEngineering Research Centre for Optoelectronic Functional Materials of Henan Province, College of Chemistry and Chemical Engineering, Shangqiu Normal University Shangqiu Henan 476000 China liuchuanzhiuniv@163.com liuchuanzhi@sqnu.edu.cn zhaibin_1978@163.com.
Liu-Xin LuoSchool of Chemistry and Chemical Engineering, State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University Shihezi Xinjiang 832003 China xuliang4423@shzu.edu.cn.
Shuang-Shuang HouEngineering Research Centre for Optoelectronic Functional Materials of Henan Province, College of Chemistry and Chemical Engineering, Shangqiu Normal University Shangqiu Henan 476000 China liuchuanzhiuniv@163.com liuchuanzhi@sqnu.edu.cn zhaibin_1978@163.com.
Song-Hao GuoEngineering Research Centre for Optoelectronic Functional Materials of Henan Province, College of Chemistry and Chemical Engineering, Shangqiu Normal University Shangqiu Henan 476000 China liuchuanzhiuniv@163.com liuchuanzhi@sqnu.edu.cn zhaibin_1978@163.com.
Meng-Ge ZhangEngineering Research Centre for Optoelectronic Functional Materials of Henan Province, College of Chemistry and Chemical Engineering, Shangqiu Normal University Shangqiu Henan 476000 China liuchuanzhiuniv@163.com liuchuanzhi@sqnu.edu.cn zhaibin_1978@163.com.
Xin-Yao PengEngineering Research Centre for Optoelectronic Functional Materials of Henan Province, College of Chemistry and Chemical Engineering, Shangqiu Normal University Shangqiu Henan 476000 China liuchuanzhiuniv@163.com liuchuanzhi@sqnu.edu.cn zhaibin_1978@163.com.
Liang XuSchool of Chemistry and Chemical Engineering, State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University Shihezi Xinjiang 832003 China xuliang4423@shzu.edu.cn.ORCID https://orcid.org/0000-0002-7939-8108 Bin ZhaiEngineering Research Centre for Optoelectronic Functional Materials of Henan Province, College of Chemistry and Chemical Engineering, Shangqiu Normal University Shangqiu Henan 476000 China liuchuanzhiuniv@163.com liuchuanzhi@sqnu.edu.cn zhaibin_1978@163.com.
Funding
No grant is acknowledged in the PubMed record.
6 · The paper itselfAbstract
In this study, a series of azo-fused H-bonded arylamide foldamers was synthesized. Molecules with extended backbones exhibited pronounced photoresponsive behavior in both dichloromethane and dimethyl sulfoxide. In low-polarity dichloromethane, intramolecular three-center hydrogen bonding remained stable, promoting the formation of well-defined S-shaped (
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PMID42125141
PMCPMC13158860
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