Study on the Effect of Temperature on Methane Catalytic Cracking over Biochar-Supported Fe.

To achieve carbon neutrality, increasing efforts have been devoted to the clean utilization of fossil fuels. This study investigates the effect of reaction temperature on methane catalytic cracking over a biochar-supported iron catalyst. Corn stalks were heated to make biochar which was used as the carrier. To obtain biochar with a high specific surface area and well-developed porous structure, chemical activation was employed. The catalyst was made by adding iron to the biochar using the soaking method. This iron biochar catalyst is used to study its effectiveness in catalyzing methane cracking. The biochar-supported Fe catalyst was studied for its effectiveness in catalyzing methane cracking at different temperatures (800-950 °C). The results indicate that a higher temperature favors methane conversion in terms of reaction efficiency and cumulative conversion levels. At 950 °C, the catalyst exhibits the best performance, with a peak conversion rate of up to 85%, and it can still maintain a stable conversion rate of around 55% after prolonged reaction, yielding the total conversion of 57.6%. Raising the temperature can significantly promote the transformation of solid-phase products from highly blocking amorphous carbon to more ordered graphitized carbon. In addition, the reacted catalyst shows a remarkably reduced specific surface area, the disappearance of micropores, and a considerable increase in average pore size. Carbon nanotubes with various diameters and morphologies were formed on the catalyst surface.