Phenothiazine: A Promising Core for Perovskite and Dye-Sensitized Solar Cells.

Photovoltaic technologies represent an increasingly relevant alternative for developing renewable energy sources, particularly those based on light-harvesting materials such as perovskite solar cells (PSCs) and dye-sensitized solar cells (DSSCs), which have achieved efficiencies of 27.3% and 13.0%, respectively. In this context, phenothiazine (PTZ) has attracted considerable interest as a structural block due to its outstanding structural and photophysical properties, which also represent low production costs and reduced environmental impact. This review presents recent advances in the design and development of phenothiazine-based organic materials for photovoltaic applications, analyzing the main synthetic routes for obtaining this nucleus, as well as the fundamental aspects related to the operation of solar cells, including relevant device parameters. Furthermore, several studies focused on the synthesis, characterization, and performance of new phenothiazine-derived molecules used in photovoltaic devices are also examined. Finally, the most relevant conclusions are discussed, and future perspectives for the use of these materials in solar technologies are proposed.