Enhancing Gypsum Plaster with Encapsulated Fischer-Tropsch Paraffin Wax as a Phase-Change Additive for Broad-Range Thermal Energy Storage.

Paraffins are attractive as phase-change materials (PCMs) due to their high latent heat capacity and adjustable phase transition temperatures. However, the individual high-purity paraffins, especially the long-chain ones, are labor-intensive and costly to produce and capable of storing and releasing latent heat only within a limited temperature range. Herein, we demonstrate the feasibility of a high-purity paraffin wax fraction (C13-C49) obtained via the Fischer-Tropsch (FT) process as a versatile latent heat storage additive within a wide range of phase transition temperatures (8.1-98.2 °C). To avoid the leakage, the FT wax was encapsulated via nanoemulsion interfacial polymerization of melamine formaldehyde (MF) shells with various core-to-monomer and melamine/formaldehyde ratios. Differential scanning calorimetry revealed that the latent heat storage capacity of the FT/MF capsules was 104.5-163.4 J/g depending on the FT loading efficiency, with the heat storage and release range of -0.7-100.2 °C and -9.8-85.8 °C, respectively. The capsules were tested as a thermoregulating additive to commercially available gypsum plaster. Unlike employment of the additives based on individual paraffins, the addition of FT/MF capsules led to a smooth reduction in heating/cooling rates of plaster layers in an extended temperature range. This makes FT/MF capsules a promising and versatile additive for a diversity of thermal energy storage applications.