ArticleOrganic letters2026
Carbonylative Synthesis of β-Trifluoromethylated Heterocyclic Ketones through 1,2-Trifluoromethylation and Minisci Carbonylation of Alkenes.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The present study details a metal-free catalytic Minisci carbonylation reaction, founded upon a radical polarity reversal strategy. The reaction under scrutiny involves the reaction of an electrophilic trifluoromethyl radical with an electron-rich alkene to generate a nucleophilic alkyl radical, which then undergoes a Minisci carbonylation transformation with various electron-deficient
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