ArticleChemical science2026
How solvent activity and solute solvation control electrode potentials: quantitative insights from Li
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
Tuning electrolyte salt concentration has emerged as a powerful strategy to enhance the performance of rechargeable batteries by mitigating parasitic side reactions. Here, we introduce a unified and quantitative validation of an electrolyte thermodynamic framework incoporated into a modified Nernst equation that explicitly includes electrolyte-specific parameters-namely, salt and solvent activities, as well as the salt hydration number-to rationalize and predict how electrode potentials vary with electrolyte concentration in reversible ion-insertion systems. We demonstrate this generic methodology for reversible Li
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