Evidence map›Paper›PMID 42095350›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Circularly Polarized Luminescent and Melt-Processable Copper(I)-Organic Glasses Based on 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl.

Zeyu Fan, Indranil Sen, Roman Pallach, Guo-Qiang Li, Andreas Steffen, Sebastian Henke

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Zeyu FanAnorganische Chemie, Fakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Dortmund, Germany.ORCID https://orcid.org/0009-0004-2431-6285
Indranil SenAnorganische Chemie, Fakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Dortmund, Germany.ORCID https://orcid.org/0009-0008-2478-7369
Roman PallachAnorganische Chemie, Fakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Dortmund, Germany.ORCID https://orcid.org/0000-0002-6578-0672
Guo-Qiang LiAnorganische Chemie, Fakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Dortmund, Germany.ORCID https://orcid.org/0009-0006-9066-1591
Andreas SteffenAnorganische Chemie, Fakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Dortmund, Germany.ORCID https://orcid.org/0000-0002-6952-7391
Sebastian HenkeAnorganische Chemie, Fakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Dortmund, Germany.ORCID https://orcid.org/0000-0003-1502-6038

Funding

Alexander von Humboldt FoundationDeutsche Forschungsgemeinschaft 535200000
6 · The paper itself

Abstract

The melting and vitrification behavior of metal-organic materials endows them with high processability, enabling the formation of bulk solids with potential in optical applications. Nevertheless, obtaining metal-organic glasses with chiroptical properties, such as circularly polarized luminescence (CPL), remains challenging due to the limited thermal and mechanical stability of current chiral metal-organic materials. Here, we report a pair of homochiral copper(I) cyanide complexes based on 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) that can be readily vitrified by either melt-quenching or desolvation. Structural analysis reveals that vitrification disrupts only the intermolecular stacking of the complexes, while preserving the local coordination environment. The resulting melt-quenched glasses are CPL-active and exhibit yellow-orange triplet excited state decay via thermally activated delayed fluorescence (TADF) at room temperature, which is environment-dependent due to an additional

Indexed as

circular polarized luminescenceglass formationmetal–organic glassthermally activated delayed fluorescencevitrification

Identifiers

PMID42095350
PMCPMC13285472

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.