ArticleChemical science2026
Overriding the radical polarity matching principle: selective chlorohydroxylation of electron-deficient alkenes enabled by Ce photocatalysis.
Luchuan Ou, Yihang Bai, Shanshuo Liu, Zongling Kan, Yu Lan, Jiali Zhu, Shihan Liu, Zhigang Ren, Shi-Jun Li, Linbin Niu
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In one paragraphArticle in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Luchuan OuCollege of Chemistry, State Key Laboratory of Antiviral Drugs and Pingyuan Laboratory, Zhengzhou University Zhengzhou Henan 450001 P. R. China lishijunzong@zzu.edu.cn nlb@zzu.edu.cn.
Yihang BaiCollege of Chemistry, State Key Laboratory of Antiviral Drugs and Pingyuan Laboratory, Zhengzhou University Zhengzhou Henan 450001 P. R. China lishijunzong@zzu.edu.cn nlb@zzu.edu.cn.
Shanshuo LiuDepartment of Infectious Diseases, State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, The First Affiliated Hospital of Zhengzhou University Zhengzhou 450052 P. R. China fccrenzg@zzu.edu.cn.
Zongling KanDepartment of Infectious Diseases, State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, The First Affiliated Hospital of Zhengzhou University Zhengzhou 450052 P. R. China fccrenzg@zzu.edu.cn.
Yu LanCollege of Chemistry, State Key Laboratory of Antiviral Drugs and Pingyuan Laboratory, Zhengzhou University Zhengzhou Henan 450001 P. R. China lishijunzong@zzu.edu.cn nlb@zzu.edu.cn.ORCID https://orcid.org/0000-0002-2328-0020 Jiali ZhuCollege of Chemistry, State Key Laboratory of Antiviral Drugs and Pingyuan Laboratory, Zhengzhou University Zhengzhou Henan 450001 P. R. China lishijunzong@zzu.edu.cn nlb@zzu.edu.cn.
Shihan LiuCollege of Chemistry and Molecular Sciences, Henan University Kaifeng 475004 P. R. China.
Zhigang RenDepartment of Infectious Diseases, State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, The First Affiliated Hospital of Zhengzhou University Zhengzhou 450052 P. R. China fccrenzg@zzu.edu.cn.
Shi-Jun LiCollege of Chemistry, State Key Laboratory of Antiviral Drugs and Pingyuan Laboratory, Zhengzhou University Zhengzhou Henan 450001 P. R. China lishijunzong@zzu.edu.cn nlb@zzu.edu.cn.ORCID https://orcid.org/0000-0001-9872-6245 Linbin NiuCollege of Chemistry, State Key Laboratory of Antiviral Drugs and Pingyuan Laboratory, Zhengzhou University Zhengzhou Henan 450001 P. R. China lishijunzong@zzu.edu.cn nlb@zzu.edu.cn.
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6 · The paper itselfAbstract
Radical addition to alkenes generally follows the polarity matching principle; for instance, the electrophilic chlorine radical favors electron-rich double bonds over electron-deficient ones in alkenes. Herein, we achieve a one-step selective aerobic chlorohydroxylation of alkenes
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PMID42094671
PMCPMC13143136
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