ArticleJournal of the American Chemical Society2026
Chirality Transfer, Memory and Sensing Activated by a Supramolecular Chiral Auxiliary Approach in Nanostructured, Tautomerically Prochiral Triptycene-Fused Benzimidazoles.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
We report the synthesis and characterization of stimuli responsive, adaptive organic chiral nanoparticles assembled using a "stereochemically fluid", triptycene-fused benzimidazole, which is chiroptically activated by the noncovalent interaction with enantiopure tartaric acid, acting as a "supramolecular chiral auxiliary". Under appropriate experimental conditions, the formation of chiral supramolecular aggregates exhibits remarkable chiroptical properties (electronic circular dichroism, ECD, and circularly polarized luminescence, CPL) with the possibility of addressing their controlled manipulation, reversion between the states, and chirality memory properties. Furthermore, the nanostructured system is capable of selective sensing of the Cu
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