ArticleScience advances2026
Super-stable two-dimensional radical conjugated metal-organic frameworks for efficient NIR-II photothermal conversion.
Article in Science advances, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
10 authors.
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Abstract
Radical-functionalized chromophores hold promise as noninvasive NIR-II agents due to their narrow HOMO-SOMO gaps, but inherent instability from radical quenching has limited their practical applications. Here, we report a molecularly engineered class of two-dimensional conjugated metal-organic frameworks (2D c-MOFs) that simultaneously integrate stable radicals (>24 months), extended π-delocalization, and metal-ligand coordination. This synergistic architecture achieves an ultrabroad NIR-II absorption peak extending beyond 1400 nm with extinction coefficients approaching ~10
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Registered trials
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