ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Unraveling Water Sorption in Single-Crystal MOFs: Insights from Spectroscopy and Modeling on the Role of Structure, Composition, and Guest Molecules.
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Understanding water sorption in metal-organic frameworks (MOFs) is essential for advancing atmospheric water harvesting (AWH). Yet, most studies rely on bulk measurements that mask intrinsic material properties and particle heterogeneity. Here, we systematically examine how defect chemistry, residual guest molecules, and metal substitution shape water uptake in MOF-801 and MOF-808 at the single-crystal level. Using bulk characterization together with in situ single-crystal Raman spectroscopy, digestion
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