ArticleInorganic chemistry2026
Axial Chirality Induction in Ferrocene-Amino Acid Hybrids─toward Chiral Redox-Active Building Blocks.
Article in Inorganic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In this paper, we report the construction of chiral ferrocene-containing (Fc) supramolecular platforms with high symmetry and well-defined geometry via dynamic covalent chemistry. Starting from amino acid hydrazides and ferrocene aldehydes, we obtained respective Fc-acylhydrazones with well-defined conformations, that display intense circular dichroism (CD) signals in the visible region associated with ferrocene-centered electronic transitions. CD and UV-vis spectroscopy, supported by computational analysis, reveal efficient transfer of chirality from the remote stereogenic centers to the Fc unit and a correlation between amino acid configuration, Fc helicity, and CD sign (l-amino acid → (
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