ArticleJournal of the American Chemical Society2026
A Twist in Electronic Relaxation of Pyrimidine Nucleosides and Nucleotides: Impact of C5 Methylation on Nonadiabatic Transition and Photohydration Damage.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
8 authors.
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Abstract
We report a combined experimental and theoretical study of the formation and decay dynamics of a ground-state twisted intermediate (TI) involved in the ultrafast internal conversion of UV-excited pyrimidine nucleosides and nucleotides in aqueous solution. Infrared transient absorption spectroscopy identifies a TI featuring a strongly twisted C5=C6 double bond, and its quantum yield (Φ
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