Evidence map›Paper›PMID 42080019›Full record

ArticleChemical science2026

How fluorine substituents strengthen aryl C-H bonds.

Daniel A Santos Oliveira, Daniela Rodrigues Silva, Ataualpa A C Braga, Célia Fonseca Guerra, Robin N Perutz, Odile Eisenstein, F Matthias Bickelhaupt

Abstract read
In one paragraph

Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Daniel A Santos OliveiraDepartment of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit Amsterdam De Boelelaan 1108 Amsterdam 1081 HZ The Netherlands f.m.bickelhaupt@vu.nl https://www.theochem.nl.ORCID https://orcid.org/0000-0002-1064-8543
Daniela Rodrigues SilvaDepartment of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit Amsterdam De Boelelaan 1108 Amsterdam 1081 HZ The Netherlands f.m.bickelhaupt@vu.nl https://www.theochem.nl.ORCID https://orcid.org/0000-0002-8191-7130
Ataualpa A C BragaDepartment of Fundamental Chemistry, Institute of Chemistry, University of São Paulo Av. Prof. Lineu Prestes, 748 São Paulo 055508-000 Brazil.ORCID https://orcid.org/0000-0001-7392-3701
Célia Fonseca GuerraDepartment of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit Amsterdam De Boelelaan 1108 Amsterdam 1081 HZ The Netherlands f.m.bickelhaupt@vu.nl https://www.theochem.nl.ORCID https://orcid.org/0000-0002-2973-5321
Robin N PerutzDepartment of Chemistry, University of York York YO10 5DD UK robin.perutz@york.ac.uk.ORCID https://orcid.org/0000-0001-6286-0282
Odile EisensteinICGM, Univ. Montpellier, CNRS, ENSCM Montpellier France odile.eisenstein@umontpellier.fr.ORCID https://orcid.org/0000-0001-5056-0311
F Matthias BickelhauptDepartment of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit Amsterdam De Boelelaan 1108 Amsterdam 1081 HZ The Netherlands f.m.bickelhaupt@vu.nl https://www.theochem.nl.ORCID https://orcid.org/0000-0003-4655-7747

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We have investigated the nature and bond dissociation energies (BDEs) of the aromatic C-H bonds in fluorinated benzenes C

Identifiers

PMID42080019
PMCPMC13133636

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.