ArticleChemical science2026
Rhodium-catalyzed atroposelective C-H fluoroallylation of heteroarenes with
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
Atroposelective C-H bond allylation represents an efficient and sustainable strategy toward construction of axially chiral functionalized biaryls. Yet existing systems are limited in reaction patterns using olefins and allyl ethers/esters. The lack of synthetic methods is ascribed to limited mechanistic pathways underlying such transformations. Reported herein is Rh(i)-catalyzed stereoconvergent axially chiral C-H fluoroalkylation of non-electron-rich arenes using racemic
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