Composition-Dependent Mechanical and Thermal Behavior of TPU-Modified PLA and ABS Filaments for FDM Applications.

Although polylactic acid (PLA) and acrylonitrile-butadiene-styrene (ABS) are among the most widely used polymers in material extrusion, their limited toughness and energy-absorption capacity often restrict the structural performance of 3D-printed functional components. To address the limited comparative understanding of how thermoplastic polyurethane (TPU) modifies the deformation behavior and phase characteristics of these two polymer systems, this study presents a multi-analytical evaluation of TPU-reinforced PLA and ABS blends. To this end, both polymers were blended with TPU at 10-50 wt% and processed into filaments via single-screw extrusion. The resulting filaments were used to fabricate ASTM D638 Type I tensile specimens via material extrusion under matrix-specific, but internally consistent, printing parameters. For each composition, five specimens were tested to obtain representative values of tensile strength, elongation at break, and toughness. In addition to conventional tensile testing, the evolution of strain during deformation was monitored using digital image correlation (DIC), enabling full-field characterization of local deformation behavior. To ensure experimental reliability, specimen masses were carefully controlled, and the datasets were analyzed using MATLAB. Thermal properties were investigated by differential scanning calorimetry (DSC) to determine the influence of TPU on glass transition, melting behavior, and phase mobility, and to relate these thermal characteristics to the mechanical response of the blends. The incorporation of TPU significantly increased ductility and energy absorption in both polymer matrices, although the magnitude of improvement differed. ABS/TPU blends exhibited the highest toughness enhancement, reaching 221.4% at 30 wt% TPU, while PLA/TPU systems showed nearly a twofold increase at 20 wt% TPU. DIC analysis further revealed a transition from localized brittle deformation in neat polymers to more distributed plastic deformation with increasing TPU content. DSC results indicated reduced crystallinity in PLA-rich blends and enhanced segmental mobility in ABS-based systems, consistent with the observed mechanical behavior. Overall, the combined mechanical, optical, and thermal analyses demonstrate that the optimal TPU content is matrix-dependent, providing practical guidelines for tailoring PLA- and ABS-based filaments to achieve a controlled balance between stiffness, ductility, and energy absorption in material extrusion applications.