Evidence map›Paper›PMID 42070067›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Forcing the Side-on π-Coordination of a C≡C Triple Bond to Technetium Using the As,CC,As Alkyne Pincer Ligand 1,2-Bis(2-(diisopropylarsaneyl)-4-(trifluoromethyl)phenyl)Ethyne.

Maximilian Roca Jungfer, Moritz Johannes Ernst, Lukas Eberle, Marius Kesselring, Guilhem Claude, Joachim Ballmann

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Maximilian Roca JungferInstitut Für Nukleare Entsorgung (INE), Karlsruher Institut für Technologie (KIT), Eggenstein-Leopoldshafen, Germany.ORCID https://orcid.org/0000-0001-7583-9634
Moritz Johannes ErnstFachbereich Biologie, Chemie, Pharmazie, Institut Für Anorganische Chemie, Freie Universität Berlin, Berlin, Germany.ORCID https://orcid.org/0000-0001-9505-8974
Lukas EberleAnorganisch Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Heidelberg, Germany.ORCID https://orcid.org/0009-0003-9723-4646
Marius KesselringFachbereich Biologie, Chemie, Pharmazie, Institut Für Anorganische Chemie, Freie Universität Berlin, Berlin, Germany.ORCID https://orcid.org/0009-0003-6944-4937
Guilhem ClaudeCorporate Member of Freie Universität Berlin and Humboldt Universität Zu Berlin, Klinik für Nuklearmedizin/Radiopharmazie, Charité - Universitätsmedizin Berlin, Berlin, Germany.ORCID https://orcid.org/0009-0000-0404-7242
Joachim BallmannAnorganisch Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Heidelberg, Germany.ORCID https://orcid.org/0000-0001-6431-4197

Funding

Baden-WürttembergDeutsche ForschungsgemeinschaftFonds der Chemischen IndustrieKarlsruhe Institute of Technology ProjectDeal
6 · The paper itself

Abstract

Alkyne complexes are known for transition metals across the d-block with exception of the radioelement technetium despite considerable synthetic efforts. DFT calculations suggest that this is not inherent to the transition metal but a consequence of the overall ligand sphere. The arsenic-based tolane ligand 1,2-bis(2-(diisopropylarsaneyl)-4-(trifluoromethyl)phenyl)ethyne (L

Indexed as

99mTcalkyneradioactiveside‐ontechnetium

Identifiers

PMID42070067
PMCPMC13266937

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.