ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Phosphorescence of Heavy, T-Shaped Pnictogen Trisamides in Solution at Room Temperature in the Near-Infrared II Region.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- T-Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond.Angewandte Chemie (International ed. in English) · 2026Article
- Phosphorescence of Heavy, T-Shaped Pnictogen Trisamides in Solution at Room Temperature in the Near-Infrared II Region.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
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5 authors.
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Abstract
We report T-shaped Sb(III) and Bi(III) trisamides that exhibit phosphorescence in the near-infrared-II region (NIR-II, 1000-1700 nm) in solution at 25 °C. Geometric constraint of the pnictogen(III) centers by an NNN pincer ligand enables ligand-to-metal charge transfer upon visible-light excitation. Significant structural reorganization upon photoexcitation leads to the largest Stokes shifts (> 6000 cm
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