ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Anion Engineering Toward Regulated Solvation Structure and Enhanced Performance in Hydrated Eutectic Electrolytes for Aluminum-Ion Batteries.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The practical deployment of rechargeable aluminum-ion batteries (AIBs) is hindered by the absence of electrolytes that concurrently offer low cost, efficient ion transport, and stable interfacial electrochemistry. While hydrated deep eutectic electrolytes (HEEs) present a promising avenue, their advancement has been limited by high viscosity and poorly controlled interfacial reactions. This work establishing anion engineering, rather than solely focusing on ligand modulation, as a critical yet previously underappreciated design strategy. We systematically elucidate how the identity of the anion governs the coordination architecture within an ethylene glycol (EG)-based HEE. Crucially, the NO
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