ArticleJournal of the American Chemical Society2026
Phosphonium Poly(Ionic Liquid) Electrolytes for Fast Lithium-Ion Conduction.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Phosphonium outperforms ammonium poly(ionic liquids) for fast ion transport polymer electrolytes.Chemical science · 2026Article
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Authors and funding
9 authors.
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Abstract
Polymer electrolytes based on ionic liquids provide a safe solution for future solid-state high-energy-density batteries. In this work, we report a novel class of solid polymer electrolytes for fast lithium-ion conduction based on phosphonium poly(ionic liquid)s (poly(IL)s). First, a new family of poly(diallyldimethylphosphonium) poly(IL)s was synthesized by cyclopolymerization of diallyldimethylphosphonium iodide following anion exchange with different sulfonamide-based anions. The characterization of the poly(IL)s confirmed the formation of a stable 5-member ring phosphonium cationic polymer backbone. Then, solid polymer electrolytes (SPEs) were prepared by doping the phosphonium sulfonamide poly(IL)s with different contents of lithium fluorosulfonamide salt (LiFSI). The nature of the ionic interactions and lithium transport of SPEs with different anion systems was deeply investigated by FTIR, DSC, ionic conductivity, solid-state
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