ArticleJournal of the American Chemical Society2026
Alkyl Radical Coupling with Phenoxy(imine)-Nickel(II)-Aryl Complexes: Evidence for a Multistep Process in C-C Bond Formation.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The reaction of well-defined phenoxy(imine)-nickel(II)-aryl complexes with alkyl radicals was investigated en route to C-C bond formation. A 4-dimethylaminopyridine-titanium tris(anilide) complex was identified as a selective reagent for halogen-atom abstraction of unactivated alkyl halides, generating alkyl radicals that were subsequently captured by phenoxy(imine)-nickel(II)-aryl complexes. A combination of radical clock and competition experiments provided insight into ligand effects on both the phenoxy(imine) and the nickel-aryl in radical capture and subsequent C-C bond formation. Differences between parallel and competition radical clock experiments support a multistep process for C-C bond formation. Results from
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