ArticleAngewandte Chemie (International ed. in English)2026
Highly Efficient Mechanochromic Thermally Activated Delayed Fluorescence in the Deep Red to Near-Infrared in Copper(I) [2.2]Isoindolinophanyl-Carbene Carbazolates.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Low energy triplet emitters are highly relevant for the development of OLEDs and fiber optics-based IT applications, but typically suffer from nonradiative decay due to the energy gap law (EGL). Excited state deactivation can be limited by enhancing the radiative decay rate via thermally activated delayed fluorescence (TADF), bypassing spin-forbidden phosphorescence. We report on linear copper(I) complexes bearing a recently reported [2.2]isoindolinophanyl-carbene (iPC) ligand as potent excited state π-acceptor. The compounds show efficient TADF from ligand-to-ligand charge transfer (
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