Evidence map›Paper›PMID 42032319›Full record

ArticleNature chemistry2026

Single-crystal to single-crystal editing of metal-organic frameworks via ligand removal.

Aleksandr Sapianik, Marina Barsukova, Aleksander Shkurenko, Mickaele Bonneau, Prashant M Bhatt, Osama Shekhah, Vincent Guillerm, Mohamed Eddaoudi

Abstract read
PubMed Publisher
In one paragraph

Article in Nature chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Aleksandr SapianikFunctional Materials Design, Discovery and Development (FMD3) Research Group, Advanced Membranes and Porous Materials Platform, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia.
Marina BarsukovaFunctional Materials Design, Discovery and Development (FMD3) Research Group, Advanced Membranes and Porous Materials Platform, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia.ORCID http://orcid.org/0000-0001-5277-8090
Aleksander ShkurenkoFunctional Materials Design, Discovery and Development (FMD3) Research Group, Advanced Membranes and Porous Materials Platform, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia.ORCID http://orcid.org/0000-0001-7136-2277
Mickaele BonneauFunctional Materials Design, Discovery and Development (FMD3) Research Group, Advanced Membranes and Porous Materials Platform, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia.
Prashant M BhattFunctional Materials Design, Discovery and Development (FMD3) Research Group, Advanced Membranes and Porous Materials Platform, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia.ORCID http://orcid.org/0000-0002-9944-1062
Osama ShekhahFunctional Materials Design, Discovery and Development (FMD3) Research Group, Advanced Membranes and Porous Materials Platform, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia.ORCID http://orcid.org/0000-0003-1861-9226
Vincent GuillermFunctional Materials Design, Discovery and Development (FMD3) Research Group, Advanced Membranes and Porous Materials Platform, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia. vguillerm@protonmail.com.ORCID http://orcid.org/0000-0003-3460-223X
Mohamed EddaoudiFunctional Materials Design, Discovery and Development (FMD3) Research Group, Advanced Membranes and Porous Materials Platform, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia. mohamed.eddaoudi@kaust.edu.sa.ORCID http://orcid.org/0000-0003-1916-9837

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Accessing metal-organic frameworks (MOFs) with wide mesopores or specific topologies sometimes requires the use of an additional ligand, termed centring structure-directing agent (cSDA), which does not alter the targeted framework's periodicity. Here we report a general strategy to remove cSDAs post-synthetically, in a single-crystal to single-crystal fashion, enabling deliberate topology transformation often associated with substantial porosity enhancement. Such window opening can be achieved through two distinct routes. The first approach, guided by Pearson's hard and soft acids and bases (HSAB) principle, uses acid treatment to release cSDAs from robust frameworks, yielding pore volumes for Cr-MOFs of up to 3.6 cm

Identifiers

PMID42032319

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.