ArticleJournal of the American Chemical Society2026
Electroreductive Radical Olefin Difunctionalization with Fluorinated Gases Enabled by Dosage Delivery from a Metal-Organic Framework.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
Funding
Abstract
Fluoroalkyl groups are crucial for tuning the pharmacokinetic properties of drug-like molecules, motivating the development of practical methods for their late-stage installation. Despite extensive progress, most contemporary fluoroalkylation strategies rely on impractical reagents or harsh reaction conditions, limiting their sustainability and scalability. Electrochemistry offers a compelling alternative by enabling controlled and tunable radical generation under mild conditions; however, electrochemical fluoroalkylation reactions, particularly reductive transformations, remain significantly underdeveloped. Herein, we report a general platform for electroreductive olefin difunctionalization that employs simple fluoroalkyl iodide gases (CF
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