ArticleJournal of water process engineering2025
Enhanced p-Nitrophenol Removal via Electrochemical Activation of Peroxymonosulfate (PMS) with Biochar in a Flow-through Reactor: Mechanistic Insights and Optimization.
Article in Journal of water process engineering, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The utilization of biochar for peroxymonosulfate (PMS) activation has gained attention due to its functional groups and porous structure. Nonetheless, its practical application is limited by challenges in regulating reaction rates and the short catalyst lifespan due to natural organic matter (NOM) and anions. Furthermore, most studies have focused on batch-type experiments. To address these limitations, this study introduced a combined electrolysis (E) and biochar (BC) system for PMS activation in a flow-through reactor to remediate dissolved p-nitrophenol (p-NP) as a model pollutant. It is hypothesized that the E-BC-PMS system enhances degradation through three mechanisms: (1) simultaneous activation of PMS by biochar and electrochemical reactions, (2) adsorption of contaminants onto biochar, and (3) formation of diverse reactive species. The E-BC-PMS system removed 99.9 % of p-NP and showed the highest removal rate constant (0.497 min
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