ArticleChemical science2026
Fast hydrated-ion transport and desolvation in pyridinyl COF membranes
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Hydrated-ion transport and desolvation dominate energy transfer and ionic selectivity in membrane separation, electrochemical energy storage, and catalytic systems, whereas achieving fast ion conduction with low hydration remains highly challenging. In this work, we discover that pyridinyl-based covalent organic framework (COF) membranes enable the fast transport of hydrated ions with efficient desolvation. This originates from a soft Lewis acid-mediated competitive coordination mechanism, where pyridinyl groups partially displace hydration shells. The ordered channels with optimized coordination not only stabilize desolvated ions but also provide continuous hopping pathways for ion migration, resulting in rapid ion transport with reduced desolvation barriers. As a proof-of-concept application, the pyridinyl COF membranes were studied in aqueous zinc batteries. Electrochemical tests reveal that partial zinc ion desolvation lowers the thermodynamic barrier for zinc nucleation, while rapid ion transport balances interfacial reaction kinetics, effectively suppressing dendrite growth and parasitic reactions. Consequently, a zinc anode paired with pyridyl COF membranes exhibits reversible stripping/plating over 2000 cycles in a conventional ZnSO
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