ArticleJournal of the American Chemical Society2026
Distance-Dependent, Rate-Accelerating and Diastereoselective Directing Effects in Decatungstate-Mediated Stereoediting Reactions.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The excited-state decatungstate (DT) polyanion is an important and commonly used hydrogen atom transfer (HAT) reagent in organic synthesis. The intrinsic site- and diastereoselectivity of DT-mediated HAT steps is broadly accepted as being dictated by steric and bond polarity (mis)matching effects, and DT's rigid polyoxometalate structure presents limited opportunities for altering this reactivity profile. Here, we reveal that innate functional groups, such as secondary amides, can accelerate the rate of HAT by DT in a proximity-dependent and diastereoselective manner. We leverage this directing effect to access
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