ArticleACS omega2026
Synthesis, Photophysical, and Chiroptical Properties of Optically Active BINOL-Boranil Enantiomers.
Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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11 authors.
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Abstract
We describe a very simple and efficient gram-scale synthetic pathway toward Boranils substituted directly on the boron center by 1,1'-bi-2-naphthol derivatives (BINOL). Properties of the resulting BINOL-Boranils were investigated by nuclear magnetic resonance (NMR), UV-visible, fluorescence, electronic circular dichroism (ECD), and circularly polarized luminescence (CPL) spectroscopies. Insight into the molecular structure is also provided based on single-crystal X-ray diffraction experiments. These chiral dyes typically feature high molar absorption coefficients in the range of 35,000 to 90,000 M
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